‘Artificial leaf’ concept inspires research into solar-powered fuel production: Rice University


A schematic and electron microscope cross-section show the structure of an integrated, solar-powered catalyst to split water into hydrogen fuel and oxygen. The module developed at Rice University can be immersed into water directly to produce fuel when exposed to sunlight. Credit: Jia Liang/Rice University

Rice University researchers have created an efficient, low-cost device that splits water to produce hydrogen fuel.

The platform developed by the Brown School of Engineering lab of Rice materials scientist Jun Lou integrates catalytic electrodes and  that, when triggered by sunlight, produce electricity. The current flows to the catalysts that turn water into hydrogen and oxygen, with a sunlight-to-hydrogen efficiency as high as 6.7%.

This sort of catalysis isn’t new, but the lab packaged a  layer and the electrodes into a single module that, when dropped into water and placed in sunlight, produces hydrogen with no further input.

The  introduced by Lou, lead author and Rice postdoctoral fellow Jia Liang and their colleagues in the American Chemical Society journal ACS Nano is a self-sustaining producer of  that, they say, should be simple to produce in bulk.

“The concept is broadly similar to an artificial leaf,” Lou said. “What we have is an integrated module that turns sunlight into electricity that drives an electrochemical reaction. It utilizes water and sunlight to get chemical fuels.”

Perovskites are crystals with cubelike lattices that are known to harvest light. The most efficient perovskite  produced so far achieve an efficiency above 25%, but the materials are expensive and tend to be stressed by light, humidity and heat.

“Jia has replaced the more expensive components, like platinum, in perovskite solar cells with alternatives like carbon,” Lou said. “That lowers the entry barrier for commercial adoption. Integrated devices like this are promising because they create a system that is sustainable. This does not require any external power to keep the module running.”

Liang said the key component may not be the perovskite but the polymer that encapsulates it, protecting the module and allowing to be immersed for long periods.

“Others have developed catalytic systems that connect the solar cell outside the water to immersed electrodes with a wire,” he said. “We simplify the system by encapsulating the perovskite layer with a Surlyn (polymer) film.”

The patterned film allows sunlight to reach the solar cell while protecting it and serves as an insulator between the cells and the electrodes, Liang said.

“With a clever system design, you can potentially make a self-sustaining loop,” Lou said. “Even when there’s no sunlight, you can use stored energy in the form of chemical fuel. You can put the hydrogen and oxygen products in separate tanks and incorporate another module like a fuel cell to turn those fuels back into electricity.”

The researchers said they will continue to improve the encapsulation technique as well as the solar themselves to raise the efficiency of the modules.

More information: Jia Liang et al, A Low-Cost and High-Efficiency Integrated Device toward Solar-Driven Water Splitting, ACS Nano (2020). DOI: 10.1021/acsnano.9b09053

Journal information: ACS Nano

Provided by Rice University

New Catalyst Recycles Greenhouse Gases into Fuel and Hydrogen Gas: KAIST and Rice University


greenhouse gas 1 ImageForNews_27007_15820400184564587

       The Korea Advanced Institute of Science and Technology (KAIST

Scientists have taken a major step toward a circular carbon economy by developing a long-lasting, economical catalyst that recycles greenhouse gases into ingredients that can be used in fuel, hydrogen gas, and other chemicals. The results could be revolutionary in the effort to reverse global warming, according to the researchers. The study was published on February 14 in Science.

“We set out to develop an effective catalyst that can convert large amounts of the greenhouse gases carbon dioxide and methane without failure,” said Cafer T. Yavuz, paper author and associate professor of chemical and biomolecular engineering and of chemistry at KAIST.

The catalyst, made from inexpensive and abundant nickel, magnesium, and molybdenum, initiates and speeds up the rate of reaction that converts carbon dioxide and methane into hydrogen gas. It can work efficiently for more than a month.

This conversion is called ‘dry reforming’, where harmful gases, such as carbon dioxide, are processed to produce more useful chemicals that could be refined for use in fuel, plastics, or even pharmaceuticals. It is an effective process, but it previously required rare and expensive metals such as platinum and rhodium to induce a brief and inefficient chemical reaction.

Other researchers had previously proposed nickel as a more economical solution, but carbon byproducts would build up and the surface nanoparticles would bind together on the cheaper metal, fundamentally changing the composition and geometry of the catalyst and rendering it useless.

“The difficulty arises from the lack of control on scores of active sites over the bulky catalysts surfaces because any refinement procedures attempted also change the nature of the catalyst itself,” Yavuz said.

The researchers produced nickel-molybdenum nanoparticles under a reductive environment in the presence of a single crystalline magnesium oxide. As the ingredients were heated under reactive gas, the nanoparticles moved on the pristine crystal surface seeking anchoring points. The resulting activated catalyst sealed its own high-energy active sites and permanently fixed the location of the nanoparticles — meaning that the nickel-based catalyst will not have a carbon build up, nor will the surface particles bind to one another. (Article continues below **)

Read More from Rice University: Rice reactor turns greenhouse gas into pure liquid fuel

Greenhouse Gas 2 0722_FUEL-1-rn

This schematic shows the electrolyzer developed at Rice to reduce carbon dioxide, a greenhouse gas, to valuable fuels. At left is a catalyst that selects for carbon dioxide and reduces it to a negatively charged formate, which is pulled through a gas diffusion layer (GDL) and the anion exchange membrane (AEM) into the central electrolyte. At the right, an oxygen evolution reaction (OER) catalyst generates positive protons from water and sends them through the cation exchange membrane (CEM). The ions recombine into formic acid or other products that are carried out of the system by deionized (DI) water and gas. Illustration by Chuan Xia and Demin Liu

 

Greenhouse Gas 20170327_pr4602_co2tocnt

 

 

(** New catalyst recycles greenhouse gases into fuel and hydrogen gas continues)

“It took us almost a year to understand the underlying mechanism,” said first author Youngdong Song, a graduate student in the Department of Chemical and Biomolecular Engineering at KAIST. “Once we studied all the chemical events in detail, we were shocked.”

The researchers dubbed the catalyst Nanocatalysts on Single Crystal Edges (NOSCE). The magnesium-oxide nanopowder comes from a finely structured form of magnesium oxide, where the molecules bind continuously to the edge. There are no breaks or defects in the surface, allowing for uniform and predictable reactions.

“Our study solves a number of challenges the catalyst community faces,” Yavuz said. “We believe the NOSCE mechanism will improve other inefficient catalytic reactions and provide even further savings of greenhouse gas emissions.”

This work was supported, in part, by the Saudi-Aramco-KAIST CO2 Management Center and the National Research Foundation of Korea.

Other contributors include Ercan Ozdemir, Sreerangappa Ramesh, Aldiar Adishev, and Saravanan Subramanian, all of whom are affiliated with the Graduate School of Energy, Environment, Water and Sustainability at KAIST; Aadesh Harale, Mohammed Albuali, Bandar Abdullah Fadhel, and Aqil Jamal, all of whom are with the Research and Development Center in Saudi Arabia; and Dohyun Moon and Sun Hee Choi, both of whom are with the Pohang Accelerator Laboratory in Korea. Ozdemir is also affiliated with the Institute of Nanotechnology at the Gebze Technical University in Turkey; Fadhel and Jamal are also affiliated with the Saudi-Armco-KAIST CO2 Management Center in Korea.


Story Source:

Materials provided by The Korea Advanced Institute of Science and Technology (KAIST)Note: Content may be edited for style and length.


Journal Reference:

  1. Youngdong Song, Ercan Ozdemir, Sreerangappa Ramesh, Aldiar Adishev, Saravanan Subramanian, Aadesh Harale, Mohammed Albuali, Bandar Abdullah Fadhel, Aqil Jamal, Dohyun Moon, Sun Hee Choi, Cafer T. Yavuz. Dry reforming of methane by stable Ni–Mo nanocatalysts on single-crystalline MgOScience, 2020; 367 (6479): 777 DOI: 10.1126/science.aav2412

A new method of extracting hydrogen from water more efficiently to capture renewable energy


Crystal structure and {MoTe}6 polyhedra showing the building blocks of each polymorph. a monoclinic 1T′-MoTe2 phase and b hexagonal 2H-MoTe2 phase. Credit: Nature Communications 10.1038/s41467-019-12831-0

A new method of extracting hydrogen from water more efficiently could help underpin the capture of renewable energy in the form of sustainable fuel, scientists say.

In a new paper, published today in the journal Nature Communications, researchers from universities in the UK, Portugal, Germany and Hungary describe how pulsing through a layered catalyst has allowed them to almost double the amount of  produced per millivolt of electricity used during the process.

Electrolysis, a process which is likely familiar to anyone who studied chemistry at , uses electric current to split the bonds between the hydrogen and oxygen atoms of water, releasing hydrogen and oxygen gas.

If the electric current for the process of electrolysis is generated through renewable means such as wind or , the entire process releases no additional carbon into the atmosphere, making no contributions to climate change. Hydrogen gas can then be used as a zero-emission fuel source in some forms of transport such as buses and cars or for heating homes.

The team’s research focused on finding a more efficient way to produce hydrogen through the electrocatalytic water splitting reaction. They discovered that electrodes covered with a molybedenum telluride catalyst showed an increase in the amount of hydrogen gas produced during the electrolysis when a specific pattern of high-current pulses was applied.

By optimising the pulses of current through the acidic electrolyte, they could reduce the amount of energy needed to make a given amount of hydrogen by nearly 50%.

Dr. Alexey Ganin, of the University of Glasgow’s School of Chemistry, directed the research team. Dr. Ganin said: “Currently the UK meets about a third of its energy production needs through renewable sources, and in Scotland that figure is about 80%.

“Experts predict that we’ll soon reach a point where we’ll be producing more renewable electricity than our consumption demands. However, as it currently stands the excess of generated energy must be used as it’s produced or else it goes to waste. It’s vital that we develop a robust suite of methods to store the  for later use.

“Batteries are one way to do that, but hydrogen is a very promising alternative. Our research provides an important new insight into producing hydrogen from electrolysis more effectively and more economically, and we’re keen to pursue this promising avenue of investigation.”

Since the level of catalytic enhancement is controlled by electric currents, recent advances in machine learning could be used to fine-tune the right sequence of applied currents to achieve the maximum output.

The next stage for the team is the development of an artificial intelligence protocol to replace human input in the search for the most effective electronic structures use in similar catalytic processes.

The paper, titled “The rapid electrochemical activation of MoTe2 for the hydrogen evolution reaction,” is published in Nature Communications

More information: The rapid electrochemical activation of MoTe2 for the hydrogen evolution reaction, Nature Communicationsdoi.org/10.1038/s41467-019-12831-0 , www.nature.com/articles/s41467-019-12831-0

Journal information: Nature Communications

Provided by University of Glasgow

Getting Real Serious About Renewable Hydrogen In Real (Heartland) America


renewable-hydrogen-from-water

Image: Two membrane-bound protein complexes work together with a synthetic catalyst to produce hydrogen from water by Olivia Johnson and Lisa Utschig via Argonne National Laboratory.

 

File this one under “W” for “When you’ve lost the heartland.” Something called the Midwest Hydrogen and Fuel Cell Coalition has just launched a mission to bring the renewable hydrogen revolution to a cluster of US states which, for reasons unknown, pop up whenever someone mentions America’s heartland, aka Real America. This is a significant development because until now, hydrogen fans have been dancing all around the perimeters of the Midwest without managing to grab a toehold.

Hydrogen is a zero-emission fuel, practically. When used in fuel cells, it produces nothing but purified water. The problem, though, is cleaning up the source of hydrogen. Currently, fossil natural gas is the primary source of hydrogen, which kind of clonks the zero emission thing in the head.

The good news is that renewable hydrogen technology is rapidly improving. One main pathway is to “split” hydrogen from water using an electrical current (aka electrolysis).

Until recent years electrolysis made no sense because coal and gas have dominated the US energy profile. The advent of low cost renewable energy has changed the game entirely.

In somewhat of an ironic twist, renewable energy critics used to complain that wind and solar were unreliable because they were intermittent. Now that very characteristic has created an opportunity for renewable hydrogen production. The basic idea is to use excess renewable energy to produce hydrogen, which then serves as a transportable energy storage medium.

Some US states have been cultivating the so-named “hydrogen economy” over the past several years, and they are already in a good position to transition from fossil-sourced hydrogen to renewables.

Leading the pack is California. The state’s ZEV (Zero Emission Vehicles) standards already call for a portion of renewable hydrogen in the mix. Eight other states — Connecticut, Maine, Maryland, Massachusetts, New Jersey, New York, Oregon, Rhode Island, and Vermont — have adopted the California ZEV model. Additionally, Colorado, Delaware, Pennsylvania, Washington, and the District of Columbia are following California’s Low Emission Vehicle standards.

So far almost all of this activity is clustered in the coastal and Northeast US states. If all goes according to plan the new MHFCC initiative will bring the hydrogen word to 12 more states smack in the nation’s midsection: Ohio, Michigan, Indiana, Wisconsin, Illinois, Minnesota, Iowa, Missouri, North and South Dakota, Nebraska, and Kansas.

Bam!

US Department Of Energy Hearts Renewable Hydrogen

Spearheading MHFCC is the US Department of Energy’s Argonne National Laboratory, in partnership with the University of Illinois Urbana-Champaign. The idea is to use the school’s decades-long foundational hydrogen and fuel cell research to jumpstart an R&D program aimed at improving electrolysis technology.

The new initiative will also leverage the Midwest’s considerable renewable energy resources. As Argonne notes, the 12 Midwest states targeted by MHFCC account for 25% of the US population and consume 30% of all electricity generated in the US.

These 12 states also lay claim to 35% of US wind capacity. So far solar has made a dismal showing in the region, but Argonne points out that major new solar projects are finally in the pipeline.

What’s Driving The Midwest Renewable Energy Train

As previously noted by CleanTechnica, the low cost of renewable energy is finally breaking through political barriers in Nebraska and other Midwest states. Considering the region’s large agricultural sector, of particular interest is the emergence of agrivoltaics, in which raised solar panels share space with grazing lands, pollinator habitats, and certain crops.

Another key factor is the Midwest’s reliance on rural electric cooperatives. RECs are becoming more engaged with renewable energy as the cost benefit comes into sharper focus, partly with an assist from the US Department of Energy.

From Renewable Energy To Renewable Hydrogen

Fans of natural gas still have a lot to cheer about. Electrolysis is not quite ready for commercial prime time, and meanwhile the demand for hydrogen is growing.

However, if all goes according to plan renewables will squeeze natural gas out of they hydrogen market in the Midwest. In announcing the new initiative, Argonne specifically states that “…the Midwestern states have some of the highest levels of renewable energy on their grids, and that “hydrogen can be used as an effective storage medium to increase utilization of these renewable energy resources.”

Sorry – not sorry.

For that matter, Argonne and the University of Illinois’s Grainger College of Engineering have already ramped up their work on electrolysis over the past couple of years.

Last fall the school described progress on a new metal-based catalyst for electrolysis. Another big breakthrough came from Argonne last winter, when the lab announced a bio-based alternative.

Also of interest is the Midwest’s relatively high nuclear energy profile. If a market for renewable hydrogen develops, nuclear power plants could continue pumping out zero emission electricity during off-peak hours and store it in the form of hydrogen.

That’s unlikely to motivate the construction of new nuclear power plants, but the use of excess nuclear energy for electrolysis could enable the region’s current fleet to operate more economically for a longer period of time (and that’s a whole ‘nother can of worms).

Interesting! CleanTechnica is reaching out to the University of Illinois to see what else is cooking in the Midwest renewable hydrogen field, so stay tuned for more on that.

The CEO Who Wants Italy to Love Hydrogen Power


A hydrogen fuel tank. Photographer: Tomohiro Ohsumi/Bloomberg

  • Snam chief says company to inject more hydrogen into system
  • Market could be worth $2.5 trillion if industry embraces gasThe

THE CEO Who Wants Italy to Love Hydrogen Power

— Read on www.bloomberg.com/amp/news/articles/2019-10-10/hydrogen-could-feed-25-of-italy-s-energy-by-2050-snam-says

Water-based fuel cell converts carbon emissions to electricity


This is a schematic illustration of Hybrid Na-CO2 System and its reaction mechanism. UNIST

Scientists from the Ulsan National Institute of Science and Technology (UNIST) developed a system which can continuously produce electrical energy and hydrogen by dissolving carbon dioxide in an aqueous solution.

The inspiration came from the fact that much of the carbon dioxide produced by humans is absorbed by the oceans, where it raises the level of acidity in the water.

Researchers used this concept to “melt” carbon dioxide in water in order to induce an electrochemical reaction. When acidity rises, the number of protons increases, and these protons attract electrons at a high rate. This can be used to create a battery system where electricity is produced by removing carbon dioxide.

The elements of the battery system are similar to a fuel cell, and include a cathode (sodium metal), a separator (NASICON), and an anode (catalyst). In this case, the catalysts are contained in the water and are connected to the cathode through a lead wire. The reaction begins when carbon dioxide is injected into the water and begins to break down into electricity and hydrogen. Not only is the electricity generated obviously useful, but the produced hydrogen could be used to fuel vehicles as well. The current efficiency of the system is up to 50 percent of the carbon dioxide being converted, which is impressive, although the system only operates on a small scale.

“Carbon capture, utilization, and sequestration (CCUS) technologies have recently received a great deal of attention for providing a pathway in dealing with global climate change,” Professor Guntae Kim of the School of Energy and Chemical Engineering at UNIST said in a statement. “The key to that technology is the easy conversion of chemically stable CO2 molecules to other materials. Our new system has solved this problem with [the] CO2 dissolution mechanism.”

A Step Closer for Clean Fuel: New Catalyst (Carbon-Based Nanocomposites) for Hydrogen Production


Flask in scientist handCarbon-based nanocomposite with embedded metal ions yields impressive performance as catalyst for electrolysis of water to generate hydrogen

A nanostructured composite material developed at UC Santa Cruz has shown impressive performance as a catalyst for the electrochemical splitting of water to produce hydrogen. An efficient, low-cost catalyst is essential for realizing the promise of hydrogen as a clean, environmentally friendly fuel.

Researchers led by Shaowei Chen, professor of chemistry and biochemistry at UC Santa Cruz, have been investigating the use of carbon-based nanostructured materials as catalysts for the reaction that generates hydrogen from water. In one recent study, they obtained good results by incorporating ruthenium ions into a sheet-like nanostructure composed of carbon nitride. Performance was further improved by combining the ruthenium-doped carbon nitride with graphene, a sheet-like form of carbon, to form a layered composite.

“The bonding chemistry of ruthenium with nitrogen in these nanostructured materials plays a key role in the high catalytic performance,” Chen said. “We also showed that the stability of the catalyst is very good.”

The new findings were published in ChemSusChem, a top journal covering sustainable chemistry and energy materials, and the paper is featured on the cover of the January 10 issue. First author Yi Peng, a graduate student in Chen’s lab, led the study and designed the cover image.

Hydrogen has long been attractive as a clean and renewable fuel. A hydrogen fuel cell powering an electric vehicle, for example, emits only water vapor. Currently, however, hydrogen production still depends heavily on fossil fuels (mostly using steam to extract it from natural gas). Finding a low-cost, efficient way to extract hydrogen from water through electrolysis would be a major breakthrough. Electricity from renewable sources such as solar and wind power, which can be intermittent and unreliable, could then be easily stored and distributed as hydrogen fuel.Figs-2A-and-2B

Polymer electrolyte membrane (PEM) water electrolysis cell Figure 2B (right): Schematic of an electrochemical energy producer. PEM hydrogen /oxygen fuel …

Currently, the most efficient catalysts for the electrochemical reaction that generates hydrogen from water are based on platinum, which is scarce and expensive. Carbon-based materials have shown promise, but their performance has not come close to that of platinum-based catalysts.

In the new composite material developed by Chen’s lab, the ruthenium ions embedded in the carbon nitride nanosheets change the distribution of electrons in the matrix, creating more active sites for the binding of protons to generate hydrogen. Adding graphene to the structure further enhances the redistribution of electrons.

water-splitting 2

 

“The graphene forms a sandwich structure with the carbon nitride nanosheets and results in further redistribution of electrons. This gives us greater proton reduction efficiencies,” Chen said.

The electrocatalytic performance of the composite was comparable to that of commercial platinum catalysts, the authors reported. Chen noted, however, that researchers still have a long way to go to achieve cheap and efficient hydrogen production.

In addition to Peng and Chen, coauthors of the study include Wanzhang Pan and Jia-En Liu at UC Santa Cruz and Nan Wang at South China University of Technology. This work was supported by the National Science Foundation and the NASA-funded Merced Nanomaterials Center for Energy and Sensing.

Story Source:

Materials provided by University of California – Santa Cruz. Original written by Tim Stephens. Note: Content may be edited for style and length.


Journal Reference:

  1. Yi Peng, Wanzhang Pan, Nan Wang, Jia-En Lu, Shaowei Chen. Ruthenium Ion-Complexed Graphitic Carbon Nitride Nanosheets Supported on Reduced Graphene Oxide as High-Performance Catalysts for Electrochemical Hydrogen EvolutionChemSusChem, 2018; 11 (1): 130 DOI: 10.1002/cssc.201701880

UCLA: Solar supercapacitor creates electricity and hydrogen fuel on the cheap


Hydrogen-powered vehicles are slowly hitting the streets, but although it’s a clean and plentiful fuel source, a lack of infrastructure for mass producing, distributing and storing hydrogen is still a major roadblock.

But new work out of the University of California, Los Angeles (UCLA) could help lower the barrier to entry for consumers, with a device that uses sunlight to produce both hydrogen and electricity.

The UCLA device is a hybrid unit that combines a supercapacitor with a hydrogen fuel cell, and runs the whole shebang on solar power.

Along with the usual positive and negative electrodes, the device has a third electrode that can either store energy electrically or use it to split water into its constituent hydrogen and oxygen atoms – a process called water electrolysis.

To make the electrodes as efficient as possible, the team maximized the amount of surface area that comes into contact with water, right down to the nanoscale. That increases the amount of hydrogen the system can produce, as well as how much energy the supercapacitor can store.

“People need fuel to run their vehicles and electricity to run their devices,” says Richard Kaner, senior author of the study. “Now you can make both fuel and electricity with a single device.”

Hydrogen itself may be clean, but producing it on a commercial scale might not be. It’s often created by converting natural gas, which not only results in a lot of carbon dioxide emissions but can be costly.

Using renewable sources like solar can help solve both of those problems at once. And it helps that the UCLA device uses materials like nickel, iron and cobalt, which are much more abundant than the precious metals like platinum that are currently used to produce hydrogen.

“Hydrogen is a great fuel for vehicles: It is the cleanest fuel known, it’s cheap and it puts no pollutants into the air – just water,” says Kaner. “And this could dramatically lower the cost of hydrogen cars.”

The new system could also help solve some of the infrastructure woes as well. Hydrogen vehicles can’t really take off until consumers can easily find places to fill up, and while strides are being made in that department, with the UCLA device users can hook into the sun almost anywhere to produce their own fuel, which could be particularly handy for those living in rural or remote areas.

As an added bonus, the supercapacitor part of the system can chemically store the harvested solar energy as hydrogen. Doing so could help bolster energy storage for the grid. Although the current device is palm-sized, the researchers say that it should be relatively easy to scale up for those applications.

The research was published in the journal Energy Storage Materials.

Source: UCLA

Solar paint offers endless energy from water vapor: Breakthrough by RMIT Researchers


Credit: CC0 Public Domain


Researchers have developed a solar paint that can absorb water vapour and split it to generate hydrogen – the cleanest source of energy.

The paint contains a newly developed compound that acts like silica gel, which is used in sachets to absorb moisture and keep food, medicines and electronics fresh and dry.

But unlike silica gel, the new material, synthetic molybdenum-sulphide, also acts as a semi-conductor and catalyses the splitting of water atoms into hydrogen and oxygen.

Lead researcher Dr Torben Daeneke, from RMIT University in Melbourne, Australia, said: “We found that mixing the compound with titanium oxide particles leads to a sunlight-absorbing paint that produces hydrogen fuel from solar energy and moist air.

“Titanium oxide is the white pigment that is already commonly used in wall paint, meaning that the simple addition of the new material can convert a brick wall into energy harvesting and fuel production real estate.

“Our new development has a big range of advantages,” he said. “There’s no need for clean or filtered water to feed the system. Any place that has water vapour in the air, even remote areas far from water, can produce fuel.”

 

His colleague, Distinguished Professor Kourosh Kalantar-zadeh, said hydrogen was the cleanest source of energy and could be used in fuel cells as well as conventional combustion engines as an alternative to fossil fuels.

“This system can also be used in very dry but hot climates near oceans. The sea water is evaporated by the hot sunlight and the vapour can then be absorbed to produce fuel.

“This is an extraordinary concept – making fuel from the sun and water vapour in the air.”

 

More information: Torben Daeneke et al, Surface Water Dependent Properties of Sulfur-Rich Molybdenum Sulfides: 
Electrolyteless Gas Phase Water Splitting, ACS Nano (2017). DOI: 10.1021/acsnano.7b01632
Provided by: RMIT University

Energy from the sun, stored in a liquid – and released on demand OR … Solar to Hydrogen Fuel … And the Winner Is?


Liquid Solar Sweeden large_RkeCoGI3VB0jjnprwamEX8rEU6kapTZ8SQd-0sN5fzs

“The solar energy business has been trying to overcome … challenge for years. The cost of installing solar panels has fallen dramatically but storing the energy produced for later use has been problematic.”

Solar Crash I solar-and-wind-energy“In a single hour, the amount of power from the sun that strikes the Earth is more than the entire world consumes in an year.” To put that in numbers, from the US Department of Energy 

 

 

Each hour 430 quintillion Joules of energy from the sun hits the Earth. That’s 430 with 18 zeroes after it! In comparison, the total amount of energy that all humans use in a year is 410 quintillion JoulesFor context, the average American home used 39 billion Joules of electricity in 2013.

HOME SOLAR-master675Read About: What are the Most Efficient Solar Panels on the Market?

 

Clearly, we have in our sun “a source of unlimited renewable energy”. But how can we best harness this resource? How can we convert and  “store” this energy resource on for sun-less days or at night time … when we also have energy needs?

Now therein lies the challenge!

Would you buy a smartphone that only worked when the sun was shining? Probably not. What it if was only half the cost of your current model: surely an upgrade would be tempting? No, thought not.

The solar energy business has been trying to overcome a similar challenge for years. The cost of installing solar panels has fallen dramatically but storing the energy produced for later use has been problematic.

 

Now scientists in Sweden have found a new way to store solar energy in chemical liquids. Although still in an early phase, with niche applications, the discovery has the potential to make solar power more practical and widespread.

Until now, solar energy storage has relied on batteries, which have improved in recent years. However, they are still bulky and expensive, and they degrade over time.

Image: Energy and Environmental Science

Trap and release solar power on demand

A research team from Chalmers University of Technology in Gothenburg made a prototype hybrid device with two parts. It’s made from silica and quartz with tiny fluid channels cut into both sections.

 

The top part is filled with a liquid that stores solar energy in the chemical bonds of a molecule. This method of storing solar energy remains stable for several months. The energy can be released as heat whenever it is required.

The lower section of the device uses sunlight to heat water which can be used immediately. This combination of storage and water heating means that over 80% of incoming sunlight is converted into usable energy.

Suddenly, solar power looks a lot more practical. Compared to traditional battery storage, the new system is more compact and should prove relatively inexpensive, according to the researchers. The technology is in the early stages of development and may not be ready for domestic and business use for some time.

 

From the lab to off-grid power stations or satellites?

The researchers wrote in the journal Energy & Environmental Science: “This energy can be transported, and delivered in very precise amounts with high reliability(…) As is the case with any new technology, initial applications will be in niches where [molecular storage] offers unique technical properties and where cost-per-joule is of lesser importance.”

A view of solar panels, set up on what will be the biggest integrated solar panel roof of the world, in a farm in Weinbourg, Eastern France February 12, 2009. Bright winter sun dissolves a blanket of snow on barn roofs to reveal a bold new sideline for farmer Jean-Luc Westphal: besides producing eggs and grains, he is to generate solar power for thousands of homes. Picture taken February 12.         To match feature FRANCE-FARMER/SOLAR              REUTERS/Vincent Kessler  (FRANCE) - RTXC0A6     Image: REUTERS: Kessler

The team now plans to test the real-world performance of the technology and estimate how much it will cost. Initially, the device could be used in off-grid power stations, extreme environments, and satellite thermal control systems.

 

Editor’s Note: As Solomon wrote in  Ecclesiastes 1:9:What has been will be again, what has been done will be done again; there is nothing new under the sun.”

Storing Solar Energy chemically and converting ‘waste heat’ has and is the subject of many research and implementation Projects around the globe. Will this method prove to be “the one?” This writer (IMHO) sees limited application, but not a broadly accepted and integrated solution.

Solar Energy to Hydrogen Fuel

So where does that leave us? We have been following the efforts of a number of Researchers/ Universities who are exploring and developing “Sunlight to Hydrogen Fuel” technologies to harness the enormous and almost inexhaustible energy source power-house … our sun! What do you think? Please leave us your Comments and we will share the results with our readers!

Read More

We have written and posted extensively about ‘Solar to Hydrogen Renewable Energy’ – here are some of our previous Posts:

Sunlight to hydrogen fuel 10-scientistsusScientists using sunlight, water to produce renewable hydrogen power

 

 

Rice logo_rice3Solar-Powered Hydrogen Fuel Cells

Researchers at Rice University are on to a relatively simple, low-cost way to pry hydrogen loose from water, using the sun as an energy source. The new system involves channeling high-energy “hot” electrons into a useful purpose before they get a chance to cool down. If the research progresses, that’s great news for the hydrogen […]

HyperSolar 16002743_1389245094451149_1664722947660779785_nHyperSolar reaches new milestone in commercial hydrogen fuel production

HyperSolar has achieved a major milestone with its hybrid technology HyperSolar, a company that specializes in combining hydrogen fuel cells with solar energy, has reached a significant milestone in terms of hydrogen production. The company harnesses the power of the sun in order to generate the electrical power needed to produce hydrogen fuel. This is […]

riceresearch-solar-water-split-090415 (1)Rice University Research Team Demonstrates Solar Water-Splitting Technology: Renewable Solar Energy + Clean – Low Cost Hydrogen Fuel

Rice University researchers have demonstrated an efficient new way to capture the energy from sunlight and convert it into clean, renewable energy by splitting water molecules. The technology, which is described online in the American Chemical Society journal Nano Letters, relies on a configuration of light-activated gold nanoparticles that harvest sunlight and transfer solar energy […]

NREL I downloadNREL Establishes World Record for Solar Hydrogen Production

NREL researchers Myles Steiner (left), John Turner, Todd Deutsch and James Young stand in front of an atmospheric pressure MDCVD reactor used to grow crystalline semiconductor structures. They are co-authors of the paper “Direct Solar-to-Hydrogen Conversion via Inverted Metamorphic Multijunction Semiconductor Architectures” published in Nature Energy. Photo by Dennis Schroeder.   Scientists at the U.S. […]

NREL CSM Solar Hydro img_0095NREL & Colorado School of Mines Researchers Capture Excess Photon Energy to Produce Solar Fuels

Photo shows a lead sulfide quantum dot solar cell. A lead sulfide quantum dot solar cell developed by researchers at NREL. Photo by Dennis Schroeder.

Scientists at the U.S. Department of Energy’s National Renewable Energy Laboratory (NREL) have developed a proof-of-principle photo-electro-chemical cell capable of capturing excess photon energy normally lost to generating heat. Using quantum […]