Radically new water splitting technique to produce hydrogen fuel


3adb215 D Burris(Nanowerk News) A University of Colorado Boulder team  has developed a radically new technique that uses the power of sunlight to  efficiently split water into its components of hydrogen and oxygen, paving the  way for the broad use of hydrogen as a clean, green fuel. The CU-Boulder team  has devised a solar-thermal system in which sunlight could be concentrated by a  vast array of mirrors onto a single point atop a central tower up to several  hundred feet tall. The tower would gather heat generated by the mirror system to  roughly 2,500 degrees Fahrenheit (1,350 Celsius), then deliver it into a reactor  containing chemical compounds known as metal oxides, said CU-Boulder Professor  Alan Weimer, research group leader.

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As a metal oxide compound heats up, it releases oxygen atoms,  changing its material composition and causing the newly formed compound to seek  out new oxygen atoms, said Weimer. The team showed that the addition of steam to  the system — which could be produced by boiling water in the reactor with the  concentrated sunlight beamed to the tower — would cause oxygen from the water  molecules to adhere to the surface of the metal oxide, freeing up hydrogen  molecules for collection as hydrogen gas.
solar thermal plant
An  artist’s conception of a commercial hydrogen production plant that uses sunlight  to split water in order to produce clean hydrogen fuel. (Image courtesy  University of Colorado Boulder)   
“We have designed something here that is very different from  other methods and frankly something that nobody thought was possible before,”  said Weimer of the chemical and biological engineering department. “Splitting  water with sunlight is the Holy Grail of a sustainable hydrogen economy.”
A paper on the subject was published in the Aug. 2 issue of  Science (“Efficient Generation of H2 by Splitting Water with an Isothermal Redox Cycle  “). The team included co-lead authors Weimer and Associate Professor Charles  Musgrave, first author and doctoral student Christopher Muhich, postdoctoral  researcher Janna Martinek, undergraduate Kayla Weston, former CU graduate  student Paul Lichty, former CU postdoctoral researcher Xinhua Liang and former  CU researcher Brian Evanko.
One of the key differences between the CU method and other  methods developed to split water is the ability to conduct two chemical  reactions at the same temperature, said Musgrave, also of the chemical and  biological engineering department. While there are no working models,  conventional theory holds that producing hydrogen through the metal oxide  process requires heating the reactor to a high temperature to remove oxygen,  then cooling it to a low temperature before injecting steam to re-oxidize the  compound in order to release hydrogen gas for collection.
“The more conventional approaches require the control of both  the switching of the temperature in the reactor from a hot to a cool state and  the introduction of steam into the system,” said Musgrave. “One of the big  innovations in our system is that there is no swing in the temperature. The  whole process is driven by either turning a steam valve on or off.”
“Just like you would use a magnifying glass to start a fire, we  can concentrate sunlight until it is really hot and use it to drive these  chemical reactions,” said Muhich. “While we can easily heat it up to more than  1,350 degrees Celsius, we want to heat it to the lowest temperature possible for  these chemical reactions to still occur. Hotter temperatures can cause rapid  thermal expansion and contraction, potentially causing damage to both the  chemical materials and to the reactors themselves.”
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A  laboratory model of a multi-tube solar reactor at the University of Colorado  Boulder that can be used to split water in order to produce clean hydrogen fuel.  (Photo courtesy University of Colorado Boulder)
In addition, the two-step conventional idea for water splitting  also wastes both time and heat, said Weimer, also a faculty member at  CU-Boulder’s BioFrontiers Institute. “There are only so many hours of sunlight  in a day,” he said.
The research was supported by the National Science Foundation  and by the U.S. Department of Energy.
With the new CU-Boulder method, the amount of hydrogen produced  for fuel cells or for storage is entirely dependent on the amount of metal oxide  — which is made up of a combination of iron, cobalt, aluminum and oxygen — and  how much steam is introduced into the system. One of the designs proposed by the  team is to build reactor tubes roughly a foot in diameter and several feet long,  fill them with the metal oxide material and stack them on top of each other. A  working system to produce a significant amount of hydrogen gas would require a  number of the tall towers to gather concentrated sunlight from several acres of  mirrors surrounding each tower.
Weimer said the new design began percolating within the team  about two years ago. “When we saw that we could use this simpler, more effective  method, it required a change in our thinking,” said Weimer. “We had to develop a  theory to explain it and make it believable and understandable to other  scientists and engineers.”

Despite the discovery, the commercialization of such a  solar-thermal reactor is likely years away. “With the price of natural gas so  low, there is no incentive to burn clean energy,” said Weimer, also the  executive director of the Colorado Center for Biorefining and Biofuels, or C2B2.  “There would have to be a substantial monetary penalty for putting carbon into  the atmosphere, or the price of fossil fuels would have to go way up.”
Source: University of Colorado at Boulder

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